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Advancing robust all-weather desalination: a critical review of emerging photothermal evaporators and hybrid systems
All-weather solar-driven desalination systems, integrating photothermal evaporators with hybrid technologies, present a sustainable, cost-effective, and high-efficiency strategy for freshwater production. Despite significant advancements, previous reviews have predominantly focused on daytime evaporation, neglecting the broader scope of all-weather seawater evaporation. This review provides a comprehensive examination of the current status of all-weather seawater evaporators and their hybrid systems. Initially, the review details the system’s composition and operating principles, as well as the design criteria for high-performance evaporators. It then goes over various common photothermal conversion materials for seawater desalination, with a particular emphasis on those materials tailored for all-weather applications. It also offers an in-depth overview to the developed photothermal hybrid systems for all-weather seawater evaporation, including their working principles, the efficiency of evaporation across the day-night cycle, and their practical applications. Lastly, the existing challenges and potential research opportunities are thoroughly discussed.
Solar-driven interfacial evaporation technologies for food, energy and water
Solar-driven interfacial evaporation technologies use solar energy to heat materials that drive water evaporation. These technologies are versatile and do not require electricity, which enables their potential application across the food, energy and water nexus. In this Review, we assess the potential of solar-driven interfacial evaporation technologies in food, energy and clean-water production, in wastewater treatment, and in resource recovery. Interfacial evaporation technologies can produce up to 5.3 l m–2 h−1 of drinking water using sunlight as the energy source. Systems designed for food production in coastal regions desalinate water to irrigate crops or wash contaminated soils. Technologies are being developed to simultaneously produce both clean energy and water through interfacial evaporation and have reached up to 204 W m–2 for electricity and 2.5 l m–2 h–1 for water in separate systems. Other solar evaporation approaches or combinations of approaches could potentially use the full solar spectrum to generate multiple products (such as water, food, electricity, heating or cooling, and/or fuels). In the future, solar evaporation technologies could aid in food, energy and water provision in low-resource or rural settings that lack reliable access to these essentials, but the systems must first undergo rigorous, scaled-up field testing to understand their performance, stability and competitiveness.
Brine management with zero and minimal liquid discharge
Zero liquid discharge (ZLD) and minimal liquid discharge (MLD) are brine management approaches that aim to reduce the environmental impacts of brine discharge and recover water for reuse. ZLD maximizes water recovery and avoids the needs for brine disposal, but is expensive and energy-intensive. MLD (which reduces the brine volume and recovers some water) has been proposed as a practical and cost-effective alternative to ZLD, but brine disposal is needed. In this Review, we examine the concepts, technologies and industrial applications of ZLD and MLD. These brine management strategies have current and potential applications in the desalination, energy, mining and semiconductor industries, all of which produce large volumes of brine. Brine concentration and crystallization in ZLD and MLD often rely on mechanical vapour compression and thermal crystallizers, which are effective but energy-intensive. Novel engineered systems for brine volume reduction and crystallization are under active development to achieve MLD and/or ZLD. These emerging systems, such as membrane distillation, electrodialytic crystallization and solvent extraction desalination, still face challenges to outcompete mechanical vapour compression and thermal crystallizers, underscoring the critical need to maximize the full potential of reverse osmosis to attain ultrahigh water recovery. Brine valorization has potential to partially offset the cost of ZLD and MLD, provided that resource recovery can be integrated into treatment trains economically and in accordance with regulations.
Winter subglacial meltwater detected in a Greenland fjord
The interaction between glacier fronts and ocean waters is one of the key uncertainties for projecting future ice mass loss. Direct observations at glacier fronts are sparse, but studies indicate that the magnitude and timing of freshwater fluxes are crucial in determining fjord circulation, ice frontal melt and ecosystem habitability. In particular, wintertime dynamics are severely understudied due to inaccessible conditions, leading to a bias towards summer observations. Here we present in situ observations of temperature and salinity acquired in late winter in Greenland at the front of a marine-terminating glacier and in surrounding fjords. Our observations indicate the existence of an anomalously fresh pool of water by the glacier front, suggesting that meltwater generated at the bed of the glacier discharges during winter. The results suggest that warm Atlantic water and nutrients are entrained at the glacier front, leading to enhanced frontal melt and increased nutrient levels. Our findings have implications for understanding the heat exchange between glacier fronts and ocean waters, glacier frontal melt rates, ocean mixing and currents, and biological productivity.
Structural stability changes of the Atlantic Meridional Overturning Circulation
The Atlantic Meridional Overturning Circulation (AMOC), a tipping climatic component, has a quasi-global impact and it could induce a cascade of critical transitions. There is considerable uncertainty regarding the location of the overturning circulation’s current state relative to its stability thresholds. We identify similarities between observational and simulated spatial patterns, bifurcation diagrams and phase spaces linked with AMOC changes. The resemblances suggest that the overturning already underwent a Hopf bifurcation and entered a bistable regime before 1854, that it suffered a Rate-induced tipping around 1970, possibly linked with the Great Salinity Anomaly, and that it approached the attractor of its weak state. These changes in the overturning circulation dynamics are indicative of complex structural stability variations during the preindustrial revolution, which underline the need for a long-term temporal assessment of the overturning circulation stability on multi-centennial to millennial time-scales, to set its contemporary and future evolution in a long-term context.
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