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Higher income is associated with greater life satisfaction, and more stress

Is there a cost to our well-being from increased affluence? Drawing upon responses from 2.05 million U.S. adults from the Gallup Daily Poll from 2008 to 2017 we find that with household income above ~$63,000 respondents are more likely to experience stress. This contrasts with the trend below this threshold, where at higher income the prevalence of stress decreases. Such a turning point for stress was also found for population sub-groups, divided by gender, race, and political affiliation. Further, we find that respondents who report prior-day stress have lower life satisfaction for all income and sub-group categories compared to the respondents who do not report prior-day stress. We find suggestive evidence that among the more satisfied, healthier, socially connected, and those not suffering basic needs deprivations, this turn-around in stress prevalence starts at lower values of income and stress. We hypothesize that stress at higher income values relates to lifestyle factors associated with affluence, rather than from known well-being deprivations related to good health and social conditions, which may arise even at lower income values if conventional needs are met.

Universal relations and bounds for fluctuations in quasistatic small heat engines

The efficiency of any heat engine, defined as the ratio of average work output to heat input, is bounded by Carnot’s celebrated result. However, this measure is insufficient to characterize the properties of miniaturized heat engines carrying non-negligible fluctuations, and a study of higher-order statistics of their energy exchanges is required. Here, we generalize Carnot’s result for reversible cycles to arbitrary order moment of the work and heat fluctuations. Our results show that, in the quasistatic limit, higher-order statistics of a small engine’s energetics depend solely on the ratio between the temperatures of the thermal baths. We further prove that our result for the second moment gives universal bounds for the ratio between the variances of work and heat for quasistatic cycles. We test this theory with our previous experimental results of a Brownian Carnot engine and observe the consistency between them, even beyond the quasistatic regime. Our results can be exploited in the design of thermal nanomachines to reduce their fluctuations of work output without marginalizing its average value and efficiency.

Advancing robust all-weather desalination: a critical review of emerging photothermal evaporators and hybrid systems

All-weather solar-driven desalination systems, integrating photothermal evaporators with hybrid technologies, present a sustainable, cost-effective, and high-efficiency strategy for freshwater production. Despite significant advancements, previous reviews have predominantly focused on daytime evaporation, neglecting the broader scope of all-weather seawater evaporation. This review provides a comprehensive examination of the current status of all-weather seawater evaporators and their hybrid systems. Initially, the review details the system’s composition and operating principles, as well as the design criteria for high-performance evaporators. It then goes over various common photothermal conversion materials for seawater desalination, with a particular emphasis on those materials tailored for all-weather applications. It also offers an in-depth overview to the developed photothermal hybrid systems for all-weather seawater evaporation, including their working principles, the efficiency of evaporation across the day-night cycle, and their practical applications. Lastly, the existing challenges and potential research opportunities are thoroughly discussed.

Diversity of biomass usage pathways to achieve emissions targets in the European energy system

Biomass is a versatile renewable energy source with applications across the energy system, but it is a limited resource and its usage needs prioritization. We use a sector-coupled European energy system model to explore near-optimal solutions for achieving emissions targets. We find that provision of biogenic carbon has higher value than bioenergy provision. Energy system costs increase by 20% if biomass is excluded at a net-negative (−110%) emissions target and by 14% at a net-zero target. Dispatchable bioelectricity covering ~1% of total electricity generation strengthens supply reliability. Otherwise, it is not crucial in which sector biomass is used, if combined with carbon capture to enable negative emissions and feedstock for e-fuel production. A shortage of renewable electricity or hydrogen supply primarily increases the value of using biomass for fuel production. Results are sensitive to upstream emissions of biomass, carbon sequestration capacity and costs of direct air capture.

Prediction of thermal conductivity in CALF-20 with first-principles accuracy via machine learning interatomic potentials

Understanding the thermal transport properties of CALF-20, a recent addition to the metal-organic framework family, is crucial for its effective utilization in greenhouse gas capture. Here, we report the thermal transport study of CALF-20 using artificial neural network-based machine learning potentials. We use the Green-Kubo approach based on equilibrium molecular dynamics, with a heat-flux renormalization technique, to determine the thermal conductivity (κ) of CALF-20. We predict that the anisotropic thermal transport in CALF-20, with κ below 1 Wm−1K−1 at 300 K, is ideal for thermoelectric applications. Our analysis reveals a weak temperature dependence (κ ~ 1/T0.56) and near invariance with pressure in κ value of CALF-20, which stands out from the typical trend observed in crystalline materials. The outcome of the study, leveraging advanced computational techniques for predictive modeling, offers valuable insights into more suitable applications of CALF-20 with tailored thermal properties.

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