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Frequency shift caused by nonuniform field and boundary relaxation in magnetic resonance and comagnetometers
In magnetic resonance experiments, it is widely recognized that a nonuniform magnetic field can lead to an increase in the resonance line width, as well as a reduction in sensitivity and spectral resolution. However, a nonuniform magnetic field can also cause shifts in resonance frequency, which has received far less attention. In this work, we investigate the frequency shift caused by boundary relaxation and nonuniform magnetic field with arbitrary spatial distribution. We find that this frequency shift is spin-species dependent, implying a systematic error in NMR gyroscopes and comagnetometers. The first order correction to this systematic error is proportional to the difference of boundary relaxation rate, and dominates for small cells. In contrast, the third and higher order corrections arise from the difference of gyromagnetic ratios of spin species, and dominates for large cells. This insight helps understanding the unexplained isotope shifts in recent NMR gyroscopes and new physics searching experiments that utilize comagnetometers. Finally, we propose a tool for wall interaction research based on the frequency shift’s dependency on boundary relaxation.
Harnessing exceptional points for ultrahigh sensitive acoustic wave sensing
Exceptional point (EP) is referred to degeneracies in a non-Hermitian system where two or more eigenvalues and their corresponding eigenvectors coalesce. Recently there have been significantly increased interests in harnessing EPs to enhance responsivities and achieve ultrasensitive detections in optics, electronics and acoustics, although there are few similar studies focused on using surface acoustic wave (SAW) sensing technologies, probably due to its great technical challenges. Herein, we proposed a scheme for accessing EPs in an on-chip architecture consisted of coupled-SAW-resonators system, forming a passive parity-time (PT) symmetric system. We demonstrated that by tuning additional losses in one of resonators and regulating the system in the proximity of the EP, the sensor exhibited significantly enhanced responses. As an example, we present an EP-based SAW gas sensor, which showed a much-improved sensitivity compared to that of a conventional delay-line SAW sensor. The fundamental mechanisms behind this excellent sensing performance have been elucidated.
Universal relations and bounds for fluctuations in quasistatic small heat engines
The efficiency of any heat engine, defined as the ratio of average work output to heat input, is bounded by Carnot’s celebrated result. However, this measure is insufficient to characterize the properties of miniaturized heat engines carrying non-negligible fluctuations, and a study of higher-order statistics of their energy exchanges is required. Here, we generalize Carnot’s result for reversible cycles to arbitrary order moment of the work and heat fluctuations. Our results show that, in the quasistatic limit, higher-order statistics of a small engine’s energetics depend solely on the ratio between the temperatures of the thermal baths. We further prove that our result for the second moment gives universal bounds for the ratio between the variances of work and heat for quasistatic cycles. We test this theory with our previous experimental results of a Brownian Carnot engine and observe the consistency between them, even beyond the quasistatic regime. Our results can be exploited in the design of thermal nanomachines to reduce their fluctuations of work output without marginalizing its average value and efficiency.
Photometric detection at 7.7 μm of a galaxy beyond redshift 14 with JWST/MIRI
The James Webb Space Telescope (JWST) has spectroscopically confirmed numerous galaxies at z > 10. While weak rest-frame ultraviolet emission lines have only been seen in a handful of sources, the stronger rest-frame optical emission lines are highly diagnostic and accessible at mid-infrared wavelengths with the Mid-Infrared Instrument (MIRI) of JWST. We report the photometric detection of the distant spectroscopically confirmed galaxy JADES-GS-z14-0 at (z=14.3{2}_{-0.20}^{+0.08}) with MIRI at 7.7 μm. The most plausible solution for the stellar-population properties is that this galaxy contains half a billion solar masses in stars with a strong burst of star formation in the most recent few million years. For this model, at least one-third of the flux at 7.7 μm originates from the rest-frame optical emission lines Hβ and/or [O iii]λλ4959, 5007. The inferred properties of JADES-GS-z14-0 suggest rapid mass assembly and metal enrichment during the earliest phases of galaxy formation. This work demonstrates the unique power of mid-infrared observations in understanding galaxies at the redshift frontier.
Full-color tuning in multi-layer core-shell nanoparticles from single-wavelength excitation
Lanthanide-based luminescent materials have shown great capabilities in addressing scientific problems encountered in diverse fields. However, achieving full-color switchable output under single-wavelength irradiation has remained a daunting challenge. Here we report a conceptual model to realize this aim by the temporal control of full upconversion evolution in a multi-layer core-shell nanostructure upon a single commercial 980-nm laser, instead of two or more excitation wavelengths as reported previously. We show that it is able to realize the red-to-green color change (from Er3+) under non-steady state excitation by constructing the cooperative modulation effect in the Er-Tm-Yb triple system, and single out the blue light (from Tm3+) by filtering out the short-decay emissions via a time-gating technique. The key role of Tm3+ in manipulating up-transition dynamics of Er3+ is further demonstrated. Our results present a deep insight into the photophysics of lanthanides, and help develop new generation of smart luminescent materials toward emerging photonic applications.
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