Synthesis of polypyrrole and its derivative nanoparticles via a surfactant-free coupling polymerization protocol
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Optical sorting: past, present and future
Optical sorting combines optical tweezers with diverse techniques, including optical spectrum, artificial intelligence (AI) and immunoassay, to endow unprecedented capabilities in particle sorting. In comparison to other methods such as microfluidics, acoustics and electrophoresis, optical sorting offers appreciable advantages in nanoscale precision, high resolution, non-invasiveness, and is becoming increasingly indispensable in fields of biophysics, chemistry, and materials science. This review aims to offer a comprehensive overview of the history, development, and perspectives of various optical sorting techniques, categorised as passive and active sorting methods. To begin, we elucidate the fundamental physics and attributes of both conventional and exotic optical forces. We then explore sorting capabilities of active optical sorting, which fuses optical tweezers with a diversity of techniques, including Raman spectroscopy and machine learning. Afterwards, we reveal the essential roles played by deterministic light fields, configured with lens systems or metasurfaces, in the passive sorting of particles based on their varying sizes and shapes, sorting resolutions and speeds. We conclude with our vision of the most promising and futuristic directions, including AI-facilitated ultrafast and bio-morphology-selective sorting. It can be envisioned that optical sorting will inevitably become a revolutionary tool in scientific research and practical biomedical applications.
A comprehensive review of KCC-1 fibrous silica for water treatment
The growing global demand for freshwater necessitates advanced water treatment technologies. This review highlights the application of fibrous silica spheres, KCC-1, in water remediation, focusing on the removal of heavy metals and organic dyes. KCC-1’s unique fibrous morphology, high surface area, and physicochemical properties make it a promising adsorbent. This work examines its synthesis, modifications, and advantages, providing insights into optimizing KCC-1-based adsorbents for sustainable water treatment.
![1-octene polymerization catalyzed by titanium and zirconium complexes supported by [PN] or [NPN] ligands](https://i2.wp.com/media.springernature.com/lw685/springer-static/image/art%3A10.1038%2Fs41428-025-01018-8/MediaObjects/41428_2025_1018_Fig1_HTML.png?w=1024&resize=1024,1024&ssl=1 "1-octene polymerization catalyzed by titanium and zirconium complexes supported by [PN] or [NPN] ligands")
1-octene polymerization catalyzed by titanium and zirconium complexes supported by [PN] or [NPN] ligands
Ligands in homogeneous complex polymerization catalysts are crucial not only for influencing polymerization activity but also for controlling the stereoselectivity of the resulting polymers. We designed ligands on the basis of the dibenzophosphole skeleton and investigated the structure and ethylene polymerization activity of titanium and zirconium complexes activated by dried modified methylaluminoxane. In this investigation, we selected 1-octene as an α-olefin monomer and polymerized it using five types of titanium and zirconium complexes. Then, we obtained information regarding the ligand structure, polymerization activity toward 1-octene, and tacticity control. The [NPN]-Zr complex, which exhibited the highest activity for ethylene polymerization, demonstrated negligible polymerization activity for 1-octene. Conversely, titanium and zirconium complexes with [PN] ligands as auxiliary ligands exhibited activity toward 1-octene, yielding isotactic-rich polyoctene.
High-throughput light-induced immunoassay with milliwatt-level laser under one-minute optical antibody-coating on nanoparticle-imprinted substrate
The efficient detection of protein biomarkers is critical for public health. However, the sensitivity of conventional antigen test kits is relatively low for early diagnosis, and laboratory immunoassays require complex pretreatment processes overnight. If target nanomaterials could be remotely guided to the detection site, simpler and faster methods would be developed. Here, we reveal the mechanism of light-induced immunoassay that anti-spike-protein antibodies for SARS-CoV-2 were coated on our developed nanoparticle-imprinted plasmonic substrate (NPI-PS) over the submillimeter area within one minute and nanoparticles modified with spike proteins can be selectively detected within a few minutes at one or two orders of higher sensitivity via a two-step optical condensation using NPI-PS. NPI-PS exhibits high-performance optical condensation with high photothermal properties even under milliwatt-class nonresonant laser irradiation, enabling a wide range of quantitative measurements. These findings support an innovative strategy to mitigate pandemic threats and various diseases through the high-throughput detection of protein biomarkers.
The spatial coupling and its influencing mechanism between rural human-habitat heritage and key rural tourism villages in China
Exploring the influencing factors and its influencing mechanism of the spatial coupling between rural human-habitat heritage (RHH) and key rural tourism villages (RTV) at county scale from the perspective of space can expand the theoretical research on the spatial coupling mechanism between RHH and RTV, and further provide theoretical reference and data support for the coordinated development and high-quality development of RHH and RTV in China. At the same time, previous studies have failed to systematically analyze the influencing factors and influencing mechanisms of the spatial coupling between RHH and RTV at the county scale, which restricted decision makers from formulating coordinated development measures between RHH and RTV at the macro level. In this study, bivariate spatial autocorrelation model and spatial coupling coordination model were used to quantitatively analyze the spatial coupling level between RHH and RTV at the county scale in China. Then, the linear regression (OLS) model, geographically weighted regression (GWR) model, and optimal parameter GeoDetector (OPGD) model were integrated to systematically analyze the linear influencing, spatial heterogeneity effect and interactive effect of natural environment and socioeconomic factors on the spatial coupling level between RHH and RTV in China, and explore the interactive influencing mechanism. The results show that the spatial coupling level of RHH and RTV in China show a significant east-west differentiation. There were 2024, 473, 293, 55 and 6 areas of severe, moderate, mild, basic and moderate coordination between RHH and RTV, respectively. Among them, severe and moderate discoordination areas are mainly distributed in Northeast China, arid and semi-arid areas in Western China, plateau areas in Southwest China, densely populated urban agglomerations and plains agricultural areas in the Middle East China. Mild discoordination areas and basic and moderate coordination areas are mainly located in transition zones in mountainous and plain areas, economically developed mountainous and hilly counties along the southeastern coast, and coastal tourist cities. Economic and population factors are the fundamental factors that affect the spatial coupling between RHH and RTV. Rural tourism facilities and rural public service facilities are important external driving forces for the coupling development of RHH and RTV, and Sociocultural environment factors are the important internal driving forces. Different surface forms, different climate conditions and different ecological environment conditions can form different natural textures and spatial organizations. Suitable climate conditions, sufficient water sources and ecological environment conditions can form more suitable rural settlement construction conditions and production and living conditions, and ultimately affect the protection and activation of rural human settlement heritage and the development and layout of key tourist villages. The spatial coupling relationship between RHH and RTV is the result of the complex interaction between the natural directivity law caused by natural environmental factors and the humanistic directivity law caused by human social and economic activities.
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